Suggestions by @jasonyoung

Udo Kier

as Baron Wolfgang Von Strucker in Captain America: The Winter Soldier (1994)

Elias Koteas

as Georges Batroc in Captain America: The Winter Soldier (1994)

Joe Pesci

as Senator Stern in Captain America: The Winter Soldier (1994)

Steve Buscemi

as Jasper Sitwell in Captain America: The Winter Soldier (1994)

Vanessa Redgrave

as Hawley in Captain America: The Winter Soldier (1994)

Kirk Douglas

as Alexander Pierce in Captain America: The Winter Soldier (1994)

Jeffrey Combs

as Arnim Zola in Captain America: The Winter Soldier (1994)

Keanu Reeves

as Bucky Barnes in Captain America: the first Avenger (1991)

Brad Pitt

as Steve Rogers in Captain America: the first Avenger (1991)

Stephen Lang

as Brock Rumlow in Captain America: The Winter Soldier (1994)

Stephen Lang

as Brock Rumlow in Captain America: Civil War (1996)

Leonardo DiCaprio

as Peter Parker in Captain America: Civil War (1996)

Mary Steenburgen

as Aunt May in Captain America: Civil War (1996)

Jennifer Connelly

as Sharon Carter in Captain America: Civil War (1996)

Jim Carrey

as Scott Lang in Captain America: Civil War (1996)

Winona Ryder

as Wanda Maximoff in Captain America: Civil War (1996)

Ralph Fiennes

as Vision in Captain America: Civil War (1996)

Wesley Snipes

as T'Challa in Captain America: Civil War (1996)

Kevin Costner

as Clint Barton in Captain America: Civil War (1996)

Eddie Murphy

as James Rhodes in Captain America: Civil War (1996)