This is the tendency of relatively calm and composed villains to lose their cool over the course of the story. Usually happens to arrogant Chessmaster-type villains (especially if said villain is a Smug Snake), as control of the situation slips from his or her grasp and things come up that they Didn't See Coming. Most notable when it happens towards the end of the story to show how pathetic the Big Bad is when things are not going exactly as planned ("This Cannot Be!"). Dirty Cowards also suffer from this, especially when they are cornered.
Fan Casting
Ratigan
Azula
Montgomery Gator
Claude Frollo
Dr. Robotnik (SatAM)
The Horned King
Bill Sykes (Oliver and Company)
King Candy
King Magnifico
Starline
Mackenzie Zales
Roxanne Wolf
Ennard
Ego (Marvel Cinematic Universe)
Prince Humperdinck
Ultron (Marvel Cinematic Universe)
Belle (Lydia the Bard's Villain Songs)
Anastasia "Anya" Romanov (Lydia the Bard's Villain Songs)
Sherman Pliskin
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